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troullier martin pseudopotential??

Posted: Sat Mar 12, 2011 9:53 am
by new_986
Hi...
Im doing LDA & GGA calculations using troullier martin pseudopotential for some of II-VI semiconductors (ZnS,ZnSe,...) but my results are not accurate comparing with other LDA & GGA results,, and when i use HGH psp my results are good for the same other input variables ,,, is troullier martin pseudopotential are always not accurate or there is something wrong with my input file?

Nawzad A.

Re: troullier martin pseudopotential??

Posted: Sun Mar 13, 2011 11:24 pm
by mverstra
Depends on the pseudopotential. In general various types of NC potentials can give comparable accuracy. PAW will be more precise.

Re: troullier martin pseudopotential??

Posted: Mon Mar 14, 2011 8:59 pm
by tetermp
Many of the Troullier-Martin pseudopotentials have core radii whose sum is greater than the typical bond length. If the cores overlap, the results are generally bad. GTH pseudopotentials will avoid this
problem, but the cutoff energy is much higher. PAW pseudopotentials offer accuracy and low cutoff, but often boxcut must be must greater than 2.

Mike

Re: troullier martin pseudopotential??

Posted: Wed Mar 16, 2011 9:58 am
by new_986
tetermp wrote:Many of the Troullier-Martin pseudopotentials have core radii whose sum is greater than the typical bond length. If the cores overlap, the results are generally bad. GTH pseudopotentials will avoid this
problem, but the cutoff energy is much higher. PAW pseudopotentials offer accuracy and low cutoff, but often boxcut must be must greater than 2.

Mike

I have GTH pseudopotentials but for LDA there are no GTH pseudopotentials for all elements in abinit website and for GGA the pspcode integer equal to 10 but in abinit should be between 1 and 8
could I change pspcode??

Nawzad A.